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Triptycene Diols: A Strategy for Synthesizing Planar pi Systems through Catalytic Conversion of a Poly(p-phenylene ethynylene) into a Poly(p-phenylene vinylene)

机译：Triptycene Diols：通过将聚（对亚苯基亚乙炔基）催化转化为聚（对亚苯基亚乙烯基）合成平面π系统的策略

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At level best: A strategic synthesis of a new class of poly(p-phenylene vinylene)-bearing annulated alkene units from a parent poly(p-phenylene ethynylene) is described (see scheme). The gold-mediated cycloisomerization reaction of alkynes with appended hydroxy-group reacting partners delivers products having a stark increase in chain rigidity and planarity, as evidenced by pronounced photophysical changes.

机译：在最好的水平上：描述了从母体聚对苯撑乙炔基战略合成一种新型的含聚对苯撑亚乙烯基环化烯烃单元的方法（参见方案）。炔烃与附加的羟基反应伙伴的金介导的环异构化反应产生的链刚性和平面度显着增加的产物，如明显的光物理变化所证明。

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作者
Swager, Timothy Manning; Vanveller, Brett Steven; Robinson, Dale;
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年度 2011
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原文格式 PDF
正文语种 en_US
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1. Triptycene Diols: A Strategy for Synthesizing Planar n Systems through Catalytic Conversion of a Poly(p-phenylene ethynylene) into a Poly(p-phenylene vinylene) [J] . Brett VanVeller, Dale Robinson, Timothy M. Swager Angewandte Chemie . 2012,第5期

机译：三并茂二醇：通过将聚对亚苯基乙炔催化转化为聚对亚苯基乙炔来合成平面n系统的策略
2. Synthesis of poly(p-phenylene vinylene)- and poly(phenylene ethynylene)-based polymers containing p-terphenyl in the main chain with alkoxyphenyl side groups [J] . Spiliopoulos IK., Mikroyannidis JA. Journal of Polymer Science, Part A. Polymer Chemistry . 2002,第15期

机译：聚（对亚苯基亚乙烯基）和聚（亚苯基乙炔）基聚合物的合成，该聚合物在主链上具有烷氧基苯基侧基，对位苯基
3. Band gap engineering for poly(p-phenylene) and poly(p-phenylene vinylene) copolymers using the tight-binding approach [J] . Giro R, Caldas MJ, Galvao DS International Journal of Quantum Chemistry . 2005,第5期

机译：使用紧密结合方法对聚对苯撑和聚对苯撑亚乙烯基共聚物进行带隙工程
4. CONVERSION OF PRECURSOR POLYMER INTO POLY(P-PHENYLENE VINYLENE) BY XeCl EXCIMER LASER [C] . Sang Yoon Paik, Seung Ho Kwon, Oh Jun Kwon, International Conference on the Science and Technology of Emissive Displays and Lighting . 2001

机译：通过Xecl准分子激光将前体聚合物转化为聚（对亚苯基乙烯基）
5. Functionalized poly(p-phenylene ethynylene)s for chemical sensing and carbon nanotube (CNT) dispersion [D] . Pourghaz, Yousef 2011

机译：用于化学传感和碳纳米管（CNT）分散的功能化聚对苯乙炔
6. Triptycene Diols: A Strategy for Planar π-Systems Demonstrated by the Catalytic Conversion of a PPE into a PPV [O] . Brett VanVeller, Dale Robinson, Timothy M. Swager -1

机译：三联碳二醇：通过PPE催化转化为PPV的平面π-系统的策略
7. Enhanced hole transport in poly(p-phenylene vinylene) planar metal-polymer-metal devices [O] . Tanase C, Blom PWM, Mulder M, 2006

机译：增强聚（对亚苯基亚乙烯基）平面金属-聚合物-金属器件中的空穴传输

Triptycene Diols: A Strategy for Synthesizing Planar pi Systems through Catalytic Conversion of a Poly(p-phenylene ethynylene) into a Poly(p-phenylene vinylene)

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